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This is very lovely and the sky is quite dramatic...If it was film, I'd ask you what type of filter you were using in the lens. As its digital, did you use the Curves command in PS, or some image editing filter?
Very pretty....

the darkening of the sky could have been done with a polarizer (don't know if digital has that option, though)

Thanx for the comments.

 

The sky is from somewhere else and was darkended by running the Auto Levels command on that layer alone. The church, which was actually shot at night under some unknow temp lighting, was altered to produce something approaching early morning (i hope).