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Canon 5D, Sunset shot not set up, just came across them and

positioned myself to catch them against the sunset.

In this case you may have been better off to have the water in focus and the figures out of focus...the lack of focus in the water combined with the way the figures are silhouetted in the reflection causes some kind of wierd "fringing" around them. Just my two cents, FWIW...

Lovely! Wonderful colours. :o)

The fringing around the people makes it looked like you just placed them there in PS.